China's Refractories ›› 2020, Vol. 29 ›› Issue (3): 24-31.DOI: 10.19691/j.cnki.1004-4493.2020.03.005
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Research Status of Non-oxides in Resin-bonded Al-Al2O3 Refractories with TiO2 Added
Yang SUN*(
), Yong LI, Yiming GUO, Jialin SUN
- School of Materials Science and Engineering, University of Science and Technology Beijing,Beijing 100083, China
-
Online:2020-09-15Published:2020-09-15 -
Contact:Yang SUN -
About author:Sun Yang is a PhD candidate in School of Materials Science and Engineering, University of Science and Technology Beijing. He obtained a master’s degree in the College of High Temperature Materials and Magnesium Resource Engineering in University of Science and Technology Liaoning in 2017. His research interests include metal composite refractories, oxide refractories and non-oxide composite refractories. He has published more than ten articles so far, nine of which have been included by SCI.
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Yang SUN, Yong LI, Yiming GUO, Jialin SUN. Research Status of Non-oxides in Resin-bonded Al-Al2O3 Refractories with TiO2 Added[J]. China's Refractories, 2020, 29(3): 24-31.
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Table 1 Properties of TiC and TiN[27]
| Properties | TiC | TiN |
|---|---|---|
| Relative molecular mass /% | 59.9 | 61.9 |
| Crystal structure | NaCl | NaCl |
| Cell parameters /nm | 0.431 8-0.432 8 | 0.424 0-0.424 9 |
| Melting point /K | 3 340-3 530 | 3 223 |
| Density /(g · cm-3) | 4.90-4.93 | 5.39-5.44 |
| Thermal conductivity / (W · m-1 · K-1) | 17-24 | 29 |
| Thermal expansion coefficient /(×106 / K) | 7.40-7.95 | 9.35 |
| Microhardness /(HV, GPa) | 30-32 | 20-20.5 |
| Elastic modulus /GPa | 315-450 | 251 |
Table 1 Properties of TiC and TiN[27]
| Properties | TiC | TiN |
|---|---|---|
| Relative molecular mass /% | 59.9 | 61.9 |
| Crystal structure | NaCl | NaCl |
| Cell parameters /nm | 0.431 8-0.432 8 | 0.424 0-0.424 9 |
| Melting point /K | 3 340-3 530 | 3 223 |
| Density /(g · cm-3) | 4.90-4.93 | 5.39-5.44 |
| Thermal conductivity / (W · m-1 · K-1) | 17-24 | 29 |
| Thermal expansion coefficient /(×106 / K) | 7.40-7.95 | 9.35 |
| Microhardness /(HV, GPa) | 30-32 | 20-20.5 |
| Elastic modulus /GPa | 315-450 | 251 |
Fig. 1 Relationship between thermodynamic stability of TiOx(s) and oxygen partial pressure
Fig. 1 Relationship between thermodynamic stability of TiOx(s) and oxygen partial pressure
Fig. 2 SEM views of brown fused alumina particle after heat treatment at 1 600 ℃ in flowing N2(g)[38]
Fig. 2 SEM views of brown fused alumina particle after heat treatment at 1 600 ℃ in flowing N2(g)[38]
Fig. 3 SEM views of Al-brown fused alumina refractories after heat treatment under high temperatures and nitrogen[38]
Fig. 3 SEM views of Al-brown fused alumina refractories after heat treatment under high temperatures and nitrogen[38]
Fig. 4 Al-Ti binary phase diagram
Fig. 4 Al-Ti binary phase diagram
Fig. 5 Thermodynamic stability of the compounds
Fig. 5 Thermodynamic stability of the compounds
Fig. 6 SEM views of Al-TiO2-Al2O3 refractories after heated at 1 000 and 1 200 ℃ in flowing N2(g)[42]
Fig. 6 SEM views of Al-TiO2-Al2O3 refractories after heated at 1 000 and 1 200 ℃ in flowing N2(g)[42]
Fig. 7 Whiskers generated around Ti(C,N) particles (a[46]) and TiN particles generated on (Al2OC)x(AlN)1-x whiskers (b[47])
Fig. 7 Whiskers generated around Ti(C,N) particles (a[46]) and TiN particles generated on (Al2OC)x(AlN)1-x whiskers (b[47])
Fig. 8 Schematic diagram of reaction process of resin-bonded Al-TiO2-Al2O3 refractories under high temperatures and nitrogen[42]
Fig. 8 Schematic diagram of reaction process of resin-bonded Al-TiO2-Al2O3 refractories under high temperatures and nitrogen[42]
Fig. 9 Schematic diagrams of the structure of Al-Al2O3 (a) and Al-TiO2-Al2O3 (b) at high temperatures
Fig. 9 Schematic diagrams of the structure of Al-Al2O3 (a) and Al-TiO2-Al2O3 (b) at high temperatures
Fig. 10 SEM views of Al-Al2O3 (a) and Al-TiO2-Al2O3 (b) refractories after heat treatment at 1 500 ℃[46]
Fig. 10 SEM views of Al-Al2O3 (a) and Al-TiO2-Al2O3 (b) refractories after heat treatment at 1 500 ℃[46]
Fig. 11 CT results of Al-TiO2-MgO-Al2O3 refractories after heat treatment at 1 500 ℃[47]
Fig. 11 CT results of Al-TiO2-MgO-Al2O3 refractories after heat treatment at 1 500 ℃[47]
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